Publications Pre-2005

List of publications from 2004 and earlier.

58. On the Preparation of ortho-Trifluoromethyl Phenyl Triflate. (a Comment)

Duncan Gill, Alison J. Hester and Guy C. Lloyd-Jones*

Org. Biomol. Chem., 2, 2547-2548, 2004

On the Preparation of ortho-Trifluoromethyl Phenyl Triflate. (a Comment)

57. Unusually Large Primary 2H/1H Kinetic Isotope Effects Accompanying a syn-β-H Elimination Reaction in a σ-Alkyl Palladium Complex

Guy C. Lloyd-Jones* and Paul A. Slatford

J. Am. Chem. Soc., 126, 2690-2691, 2004

Unusually Large Primary 2H/1H Kinetic Isotope Effects Accompanying a syn-β-H Elimination Reaction in a σ-Alkyl Palladium Complex

56. Mechanistic Studies of The Molybdenum-catalyzed Asymmetric Alkylation Reaction

David L. Hughes*, Guy C. Lloyd-Jones*, Shane W. Krska*, Laure Gouriou, Veronique D. Bonnet, Kevin Jack, Yongkui Sun and Robert A Reamer

Proc. Nat. Acad. Sci., 101, 5379-5384, 2004

Mechanistic Studies of The Molybdenum-catalyzed Asymmetric Alkylation Reaction

55. Conclusive Evidence for a Retention-Retention Pathway for the Molybdenum-Catalyzed Asymmetric Alkylation

Guy C. Lloyd-Jones,* Shane W. Krska,* David L. Hughes,* Laure Gouriou, Veronique D. Bonnet, Kevin Jack, Yongkui Sun and Robert A Reamer

J. Am. Chem. Soc., 126, 702-703, 2004

Conclusive Evidence for a Retention-Retention Pathway for the Molybdenum-Catalyzed Asymmetric Alkylation

54. Isotopic Desymmetrization in the Study of Homogeneous Catalysis

Ian J. S. Fairlamb, Guy C. Lloyd-Jones*, Aina Martorell, Martin Murray*, Susanna C. Stephen and Paula M. Tomlin

Phosphorus, Sulfur Silicon Relat. Elem., 179, 907-910, 2004

Isotopic Desymmetrization in the Study of Homogeneous Catalysis

53. Coordination of the Trost Modular Ligand to Palladium Allyl Fragments: Oligomers, Monomers and Memory Effects in Catalysis

Guy C. Lloyd-Jones,* Susanna C. Stephen, Ian J. S. Fairlamb, Aina Martorell, Beatriz Dominguez, Paula M. Tomlin, Martin Murray, Jesus M. Fernandez, John C. Jeffery , Thomas Riis-Johennessen, and Toufik Guerziz

Pure Appl. Chem., 76, 589-601, 2004

Coordination of the Trost Modular Ligand to Palladium Allyl Fragments: Oligomers, Monomers and Memory Effects in Catalysis

52. Organic Aspects of Organometallic Chemistry

Guy C. Lloyd-Jones

Specialist Periodical Reports, 31, 209-278, 2004

Organic Aspects of Organometallic Chemistry

51. 2H-Quadrupolar Coupling-based Analysis of Stereochemical and Regiochemical Memory in the Pd-catalysed Allylic Alkylation of iso-Cinnamyl type Substrates Employing the Chiral Monophosphine Ligands 'MOP' and 'MAP'

Laure Gouriou, Guy C. Lloyd-Jones,* Stepan Vyskocil and Pavel Kocovský

J. Organomet. Chem., 687, 525-537, 2004

H-Quadrupolar Coupling-based Analysis of Stereochemical and Regiochemical Memory in the Pd-catalysed Allylic Alkylation of iso-Cinnamyl type Substrates Employing the Chiral Monophosphine Ligands 'MOP' and 'MAP'

50. Scalar coupling between the 15N centres in methylated 1,8-diaminonaphthalenes and 1,6-diazacyclodecane: to what extent is 2HJNN a reliable indicator of N-N distance?

Guy C. Lloyd-Jones,* Jeremy N. Harvey*, Paul Hodgson, Martin Murray and Robert L. Woodward

Chem. Eur. J., 9, 4523-4535, 2003

to what extent is 2HJNN a reliable indicator of N-N distance?

49. Highlights from the 38th ESF/EUCHEM Conference on Stereochemistry, Bürgenstock, Switzerland, April/May 2003

Mathew Gaunt and Guy C. Lloyd-Jones

Chem. Commun., 2253-2255, 2003

Highlights from the 38th ESF/EUCHEM Conference on Stereochemistry, Bürgenstock, Switzerland, April/May 2003

48. Modification of the Atropisomeric N,N-Ligand 2,2′-bis(Pyridin-2-yl)-1,1′-binaphthalene and its Application to the Asymmetric Allylation of Benzaldehyde

Jonathan P. H. Charmant, Neil J. Hunt, Guy C. Lloyd-Jones* and Thorsten Nowak

Collect. Czech. Chem. Commun., 68, 865-884, 2003

Modification of the Atropisomeric N,N-Ligand

47. The Anionic Thia-Fries Rearrangement of Aryl Triflates

Jonathan P. H. Charmant, Alan M. Dyke and Guy C. Lloyd-Jones*

Chem. Commun., 380-381, 2003

The Anionic Thia-Fries Rearrangement of Aryl Triflates

46. Mechanistic Aspects of Transition Metal Catalysed 1,6-Diene and 1,6-Enyne Cycloisomerisation Reactions

Guy C. Lloyd-Jones

Org. Biomol. Chem., 1, 215-236, 2003

Mechanistic Aspects of Transition Metal Catalysed 1,6-Diene and 1,6-Enyne Cycloisomerisation Reactions

45. Analysis of Stereochemical Convergence in Asymmetric Pd-Catalysed Allylic Alkylation Reactions Complicated by Halide and Memory Effects

Ian J. S. Fairlamb, Guy C. Lloyd-Jones*, Stephan Vyskocil and Pavel Kocovský

Chem. Eur. J., 8, 4443-4453, 2002

Analysis of Stereochemical Convergence in Asymmetric Pd-Catalysed Allylic Alkylation Reactions

44. Highlight: Palladium-catalysed α-Arylation of Esters: Ideal New Methodology for Discovery Chemistry

Guy C. Lloyd-Jones

Angew. Chem. Int. Ed., 41, 953-956, 2002

Highlight: Palladium-catalysed α-Arylation of Esters: Ideal New Methodology for Discovery Chemistry

43. Convenient, Rapid and Highly Regioselective Cycloisomerisation of 4,4-Disubstituted Hepta-1,6-dienes Employing Neutral Palladium-Chloride pro-Catalysts

Katharine L. Bray, Ian J. S. Fairlamb, Jan-Phillip Kaiser, Guy C. Lloyd-Jones* and Paul A. Slatford

Topics in Catalysis, 19, 49-59, 2002

Convenient, Rapid and Highly Regioselective Cycloisomerisation

42. Testing Racemic Chiral Catalysts for Kinetic Resolution Potential

Beatriz Dominguez, Neil S. Hodnett, Guy C. Lloyd-Jones*

Angew. Chem. Int. Ed., 40, 4289-4291, 2001

Testing Racemic Chiral Catalysts for Kinetic Resolution Potential

41. Organometallic chemistry. Part (ii) Transition metals in organic synthesis–stoichiometric applications

Beatriz Dominguez, Neil S. Hodnett, Guy C. Lloyd-Jones*

Annu. Rep. Prog. Chem., Sect. B: Org. Chem., 97, 113-141, 2001

Organometallic chemistry

40. Structural and Mechanistic Studies of the Activation and Propagation of a Cationic Allyl-Pd pro-catalyst in 1,6-diene Cycloisomerisation

Katharine L. Bray, Ian J. S. Fairlamb, Jonathan P. H. Charmant, Guy C. Lloyd-Jones*

Chem. Eur. J., 7, 4205-4215, 2001

Structural and Mechanistic Studies of the Activation and Propagation of a Cationic Allyl-Pd pro-catalyst in 1,6-diene Cycloisomerisation

39. Halide redistribution in Pd-catalysed 1,6-diene cycloisomerisation

Katharine L. Bray, Ian J. S. Fairlamb, Guy C. Lloyd-Jones*

Chem. Commun., 187-188, 2001

Highlighted in Chemistry and Industry, 2001, 316-317

Halide redistribution in Pd-catalysed 1,6-diene cycloisomerisation

38. Synthesis of [2H, 13C]-labelled Diallylmalonates - Useful Probes for the Study of Transition Metal catalysed 1,6-diene Cycloisomerisation

Katharine L. Bray, Guy C. Lloyd-Jones*

Eur. J. Org. Chem., 1635-1642, 2001

Useful Probes for the Study of Transition Metal catalysed 1,6-diene Cycloisomerisation

37. On the Evidence for Formation of an exo-π-Allyl Complex Intermediate in the Pd0-Catalysed Alkylation of a Bicyclic Allylic Diacetate

Guy C. Lloyd-Jones

Eur. J. Org. Chem., 1005-1007, 2001

On the Evidence for Formation of an exo-π-Allyl Complex Intermediate in the Pd0-Catalysed Alkylation of a Bicyclic Allylic Diacetate

36. Isotopic Desymmetrisation as a Stereochemical Probe

Guy C. Lloyd-Jones

Synlett (Account), 161-183, 2001

Isotopic Desymmetrisation as a Stereochemical Probe

35. Entropy-Driven Hydrogen Bonding: Stereodynamics of a Protonated, N,N-Chiral "Proton Sponge"

Paul Hodgson, Guy C. Lloyd-Jones*, Martin Murray, Torren M. Peakman and Robert L. Woodward

Chem. Eur. J., 6, 4451-4460, 2000

Entropy-Driven Hydrogen Bonding

34. On the effect of catalyst loading in Pd-catalysed allylic alkylation

Ian J. S. Fairlamb and Guy C. Lloyd-Jones*

Chem. Commun., 2447-2448, 2000

On the effect of catalyst loading in Pd-catalysed allylic alkylation

33. Organometallic chemistry. Part (ii) Transition metals in organic synthesis–stoichiometric applications

Guy C. Lloyd-Jones

Ann. Rep. Prog. Chem. B, 96, 107-130, 2000

Organometallic chemistry.

32. Diastereoisomeric Cationic π-allyl-Pd-(P,C)-MAP and MOP Complexes and their Relationshipto Stereochemical Memory Effects in Allylic Alkylation

Guy C. Lloyd-Jones*, Susanna C. Stephen, Martin Murray, Craig P. Butts, Stepan Vyskocil* and Pavel Kocovský*

Chem. Eur. J., 6, 4348-4357, 2000

Diastereoisomeric Cationic π-allyl-Pd-(P,C)-MAP and MOP Complexes

31. Ligand Exchange and Stereodynamics in the Cationic Pd(II)-π-allyl Complex of 2,2′-bis(Pyridyl)-1,1′-binaphthalene, a Novel Atropisomeric N,N-Ligand

Jonathan P. H. Charmant, Ian A. Fallis, Neil J. Hunt, Guy C. Lloyd-Jones*, Martin Murray and Thorsten Nowak

J. Chem. Soc., Dalton Trans., 1723-1732, 2000

a Novel Atropisomeric N,N-Ligand

30. Powerful Kinetic Diastereoselection in Ruthenium-catalysed Ring-closing Methathesis of Homoallyl Vinyl Cyclopropanes

Guy C. Lloyd-Jones*, Martin Murray, Rosie A. Stentiford and Paul A. Worthington

Eur. J. Org. Chem., 975-985, 2000

Powerful Kinetic Diastereoselection in Ruthenium-catalysed Ring-closing Methathesis of Homoallyl Vinyl Cyclopropanes

28. Robust and Catalytically Active Mono- and Bis-Pd Complexes of the 'Trost Modular Ligand'

Craig P. Butts, John Crosby, Guy C. Lloyd-Jones* and Susanna C. Stephen

Chem. Commun., 1707-1708, 2000

Robust and Catalytically Active Mono- and Bis-Pd Complexes of the 'Trost Modular Ligand'

27. Organometallic chemistry . Part (ii) Transition metals in organic synthesis – stoichiometric applications

Guy C. Lloyd-Jones

Ann. Rep. Prog. Chem. B., 95, 117-136, 1999

Organometallic chemistry . Part (ii) Transition metals in organic synthesis – stoichiometric applications

26. Transition Metal Catalysis in Organic Syntheis: Reflections, Chirality, and New Vistas

Pavel Kocovsky*, Andrei Malkov, Stepan Vyskocil and Guy C. Lloyd-Jones

Pure Appl. Chem., 71, 1425-1433, 1999

Transition Metal Catalysis in Organic Syntheis: Reflections, Chirality, and New Vistas

25. Palladium(II) Complexes of 2-Dimethylamino-2′-diphenylphosphino-1,1′-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig–Buchwald Amination, and Suzuki Coupling

Pavel Kocovsky*, Stepan Vyskocil*, Ivana Cisarova, Jan Srjbal, Iva Tislerova, Marticn Smrcina, Guy C. Lloyd-Jones*, Susanna C. Stephen, Craig P. Butts, Martin Murray and Vratislav Langer

J. Am. Chem. Soc., 121, 7714-7715, 1999

Palladium(II) Complexes

24. Synthesis, Structure and Stereodynamics of an N,N-Chiral 'Proton Sponge'

Jonathan P. H. Charmant, Guy C. Lloyd-Jones*, Torren M. Peakman and Robert L. Woodward

Eur. J. Org. Chem., 2, 2501-2510, 1999

Synthesis, Structure and Stereodynamics of an N,N-Chiral 'Proton Sponge'

23. Stable Palladium Catalyst

Guy C. Lloyd-Jones

UK Patent application, 1999

Empty benzene ring

22. Chloride Ion Effects on Kinetic Resolution in Pd-Catalysed Allylic Substitution

Guy C. Lloyd-Jones* and Susanna C. Stephen

Chem. Commun., 2321-2322, 1998

Chloride Ion Effects on Kinetic Resolution in Pd-Catalysed Allylic Substitution

21. Organometallic chemistry. Part (ii) Stoichiometric methods

Guy C. Lloyd-Jones

Ann. Rep. Prog. Chem. B., 94, 105-127, 1998

Organometallic chemistry. Part (ii) Stoichiometric methods

20. Kinetic Diastereoselection of Homoallylic Indium Alkoxides: Syn Crotylation of Arylaldehydes

Guy C. Lloyd-Jones* and Tim Russell

Synlett, 903-905, 1998

Kinetic Diastereoselection of Homoallylic Indium Alkoxides: Syn Crotylation of Arylaldehydes

19. Memory Effects in Pd-Catalysed Allylic Alkylation: Stereochemical Labelling Through Isotopic Desymmetrization

Guy C. Lloyd-Jones* and Susanna C. Stephen

Chem. Eur. J., 4, 2539-2549, 1998

Memory Effects in Pd-Catalysed Allylic Alkylation: Stereochemical Labelling Through Isotopic Desymmetrization

18. Synthesis of a Protonated C2-Symmetric N,N-Chiral "Proton Sponge"

Jonathan P. H. Charmant, Guy C. Lloyd-Jones*, Torren M. Peakman and Robert L. Woodward

Tetrahedron Lett., 39, 4733-4736, 1998

Synthesis of a Protonated C2-Symmetric N,N-Chiral "Proton Sponge"

17. Perfect Complementarity in the Fitting of Two Homochiral Heterodonor Ligands Around a Nickel(II) Centre: an 'Intramolecular Embrace'

Katherine L. Bray, Craig P. Butts, Guy C. Lloyd-Jones* and Martin Murray

Dalton Trans., 1421-1422, 1998

Perfect Complementarity in the Fitting of Two Homochiral Heterodonor Ligands Around a Nickel(II) Centre: an 'Intramolecular Embrace'

16. Homoallyl-Substituted Vinylcyclopropanes from α,β-Unsaturated Ketones and Allylindium Derivatives

(Homoallyl-substituierte Vinylcyclopropane aus α,β-ungesättigten Ketonen und Allylindium-Derivaten)

Henning A. F. Höppe, Guy C. Lloyd-Jones*, Martin Murray, Torren M. Peakman and Kenneth E. Walsh

Angew. Chem., 110, 1653-1655, 1998Angew. Chem. Int. Ed. Engl., 37, 545–1547, 1998

Homoallyl-Substituted Vinylcyclopropanes from α,β-Unsaturated Ketones and Allylindium Derivatives

15. Regioselectivity and Diastereoselectivity in the Indium-mediated Homoallyl-Cyclopropanation of Dibenzylidene Acetone (dba)

Steven M. Capps, Torren M. Peakman, Guy C. Lloyd-Jones,* Martin Murray and Kenneth E. Walsh

Tetrahedron Lett., 39, 2853-2856, 1998

Regioselectivity and Diastereoselectivity in the Indium-mediated Homoallyl-Cyclopropanation of Dibenzylidene Acetone (dba)

14. Nickel(II) Complexes Bearing Phosphinoaryl Oxazoline Ligands as Pro-catalysts for Grignard Cross-Coupling

Guy C. Lloyd-Jones* and Craig P. Butts

Tetrahedron, 54, 901-914, 1998

Nickel(II) Complexes Bearing Phosphinoaryl Oxazoline Ligands as Pro-catalysts for Grignard Cross-Coupling

13. Regiocontrol and Stereoselectivity in Tungsten-Bypridine Catalysed Allylic Alkylation

Jürg Lehmann and Guy C. Lloyd-Jones*

Tetrahedron, 51, 8863–8874, 1995

Regiocontrol and Stereoselectivity in Tungsten-Bypridine Catalysed Allylic Alkylation

12. Enantio- and Regiocontrol in Palladium- and Tungsten-Catalyzed Allylic Substitutions

Roger Prétôt, Guy. C. Lloyd-Jones and Andreas Pfaltz*

Pure & Appl. Chem., 70, 1035–1049, 1998

Enantio- and Regiocontrol in Palladium- and Tungsten-Catalyzed Allylic Substitutions

11. Enantioselective Allylic Substitution Catalyzed by Chiral Bisoxazoline Pd Complexes: Catalyst Structure and Possible Mechanism of Enantioselection

Peter von Matt, Guy C. Lloyd-Jones, Alexander B. E. Minidis, Andreas Pfaltz*, Ludwig Macko, Markus Neuburger, Margareta Zehnder, Heinz Rüegger and Paul S. Pregosin*

Helv. Chim. Acta., 78, 265–284, 1995

Enantioselective Allylic Substitution Catalyzed by Chiral Bisoxazoline Pd Complexes: Catalyst Structure and Possible Mechanism of Enantioselection

10. Synthesis of Chiral Phosphinoaryl oxazolines, a Versatile Class of Ligands for Asymmetric Catalysis

Guido Koch, Guy. C. Lloyd-Jones, Olivier Loiseleur, Andreas Pfaltz*, Roger Prétôt, Silvia Schaffner, Patrick Schneider and Peter von Matt

Recl. Trav. Chim. Pay-Bas, 114, 206–210, 1995

Synthesis of Chiral Phosphinoaryl oxazolines, a Versatile Class of Ligands for Asymmetric Catalysis

9. Synthesis and Structures of Low-Valent Tungsten Complexes Bearing Chiral Oxazoline-Derived Ligands

Guy. C. Lloyd-Jones and Andreas Pfaltz*

Z. Naturforsch. B, 50, 361–367, 1995

Synthesis and Structures of Low-Valent Tungsten Complexes Bearing Chiral Oxazoline-Derived Ligands

8. Chiral Phosphanodihydrooxazoles in Asymmetric Catalysis: Tungsten-Catalyzed Allylic Substitution

Guy. C. Lloyd-Jones and Andreas Pfaltz*

Angew. Chem., 107, 534–536, 1995Angew. Chem. Int. Ed. Engl., 34, 462–464, 1995

Chiral Phosphanodihydrooxazoles in Asymmetric Catalysis: Tungsten-Catalyzed Allylic Substitution

7. Mechanism and Synthesis in Catalytic Hydroboration

John M. Brown*, Henri Doucet, Elana Fernadez, H. Eric Heeres, Mark, W. Hooper, David I. Hulmes, Frances I. Knight. Timothy P. Layzell and Guy C. Lloyd-Jones

Organometallics in Organic Synthesis, 'Chemistry in the 21st Century' series, Blackwell, Oxford, 1998

Empty benzene ring

6. Vinylborane Formation in Rhodium-Catalyzed Hydroboration of Vinylarenes. Mechanism versus Borane Structure and Relationship to Silation

John M. Brown* and Guy C. Lloyd-Jones

J. Am. Chem. Soc., 116, 866–878, 1994

Vinylborane Formation in Rhodium-Catalyzed Hydroboration of Vinylarenes. Mechanism versus Borane Structure and Relationship to Silation

5. Reversible Dimerisation of Ephedrine-derived Oxazaborolidines

John M. Brown*, Guy C. Lloyd-Jones and Timothy. P. Layzel

Tetrahedron: Asymmetry, 4, 2151–2154, 1993

Reversible Dimerisation of Ephedrine-derived Oxazaborolidines

4. Vinylborane Formation in Rhodium-catalysed Hydroborations; Ligand-free Homogeneous Catalysis

John M. Brown*, Simon. W. Leppard and Guy C. Lloyd-Jones

J. Chem. Soc., Chem. Commun., 710–712, 1992

Vinylborane Formation in Rhodium-catalysed Hydroborations; Ligand-free Homogeneous Catalysis

3. A Rapid Assay for the Enantiomeric Purity of Secondary Alcohols using 4S,5R-4-methyl,5-phenyl-1,3,2-oxazaborolidine (Ephedrineborane)

John M. Brown*, Simon. W. Leppard and Guy C. Lloyd-Jones

Tetrahedron: Asymmetry, 3, 261–266, 1992

A Rapid Assay for the Enantiomeric Purity of Secondary Alcohols using 4S,5R-4-methyl,5-phenyl-1,3,2-oxazaborolidine (Ephedrineborane)

2. Control Factors for Selective Homogeneous Catalysis

J. M. Brown*, J. V. Carey, A. D. Conn, G. C. Lloyd-Jones and S. C. Woodward

Advances in Catalyst Design, World Scientific Press, Singapore, 1991

Empty benzene ring

1. Catalytic Asymmetric Hydroboration with Oxazaborolidines

John M. Brown and Guy C. Lloyd-Jones

Tetrahedron: Asymmetry, 1, 27–47, 1990

Catalytic Asymmetric Hydroboration with Oxazaborolidines

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