Single‐Crystal X‐Ray Diffraction Study of Pressure and Temperature‐Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework

A new paper by Simon Parsons on "Single‐Crystal X‐Ray Diffraction Study of Pressure and Temperature‐Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework" has been published in Angewandte Chemie.

High‐pressure single‐crystal X‐ray diffraction has been used to trap both the low‐spin (LS) and high‐spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII(pdm)(H2O)[Ag(CN)2]2⋅H2O, under identical experimental conditions, allowing the structural changes arising from the spin‐transition to be deconvoluted from previously reported thermal effects.

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