Publications 2015-2019

A list of all the group's publications from 2015-2019.

2019

161. Suzuki–Miyaura Cross‐Coupling

Alexander B. Pagett and Guy C. Lloyd-Jones*

Organic Reactions, Volume 100, 2019

Suzuki–Miyaura Cross‐Coupling

160. Kinetics and Mechanism of the Arase-Hoshi R2BH-Catalyzed Alkyne Hydroboration: Alkenylboronate generation via B-H/C-B Metathesis

Eduardo Nieto-Sepulveda, Andrew D. Bage, Louise A. Evans, Thomas A. Hunt, Andrew G. Leach, Stephen P. Thomas*, and Guy C. Lloyd-Jones*

J. Am. Chem. Soc., 141, 18600–18611, 2019

Highlighted in JACS Spotlights "New Study Reveals Kinetics and Mechanism of Catalyzed Alkyne Hydroboration"

Kinetics and Mechanism of the Arase-Hoshi R2BH-Catalyzed Alkyne Hydroboration: Alkenylboronate generation via B-H/C-B Metathesis

159. Kinetic analysis of bioorthogonal reaction mechanisms using Raman microscopy

William J. Tipping, Martin Lee, Valerie G. Brunton, Guy C. Lloyd-Jones and Alison N. Hulme*

Faraday Discuss., 220, 71–85, 2019

Kinetic analysis of bioorthogonal reaction mechanisms using Raman microscopy

158. Gold-Catalyzed Oxidative Coupling of Arenes and Arylsilanes

Chris Nottingham, Verity Barber, and Guy C. Lloyd-Jones*

Organic Syntheses, 96, 150–178, 2019

Gold-Catalyzed Oxidative Coupling of Arenes and Arylsilanes

157. Kinetics of Initiation of the Third Generation Grubbs Metathesis Catalyst: Convergent Associative and Dissociative Pathways

Veronica Forcina, Andres Garcia-Dominguez, and Guy C. Lloyd-Jones*

Faraday Discussions, 220, 179–195, 2019

Kinetics of Initiation of the Third Generation Grubbs Metathesis Catalyst: Convergent Associative and Dissociative Pathways

156. Taming Ambident Triazole Anions: Regioselective Ion-Pairing Catalyzes Direct N-Alkylation with Atypical Regioselectivity

Harvey J. A. Dale, George R. Hodges, and Guy C. Lloyd-Jones*

J. Am. Chem. Soc., 141, 7181–7193, 2019

Taming Ambident Triazole Anions: Regioselective Ion-Pairing Catalyzes Direct N-Alkylation with Atypical Regioselectivity

155. Dehydropolymerization of H3B·NMeH2 using a [Rh(DPEphos)]+ catalyst: The promoting effect of NMeH2

Gemma Adams, David Ryan, Nicholas Beattie, Alasdair McKay, Guy Lloyd-Jones and Andrew Weller*

ACS Catal., 9, 3657–3666, 2019

 Dehydropolymerization of H3B·NMeH2 using a [Rh(DPEphos)]+ catalyst: The promoting effect of NMeH2

2018

154. Trimethylsilyldiazo[13C]methane: A Versatile 13C-Labelling Reagent

Chris Nottingham and Guy C. Lloyd-Jones*

Org. Synth., 95, 374-402, 2018

Trimethylsilyldiazo[13C]methane: A Versatile 13C-Labelling Reagent

153. Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR

Craig P. Johnston, Thomas H. West, Ruth E. Dooley, Marc Reid, Ariana B. Jones, Edward J. King, Andrew G. Leach, and Guy C. Lloyd-Jones*

J. Am. Chem. Soc., 140, 11112-11124, 2018

Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR

152. Analysis of Auto-induction, Inhibition and Auto-Inhibition in a Rh-Catalyzed C-C Cleavage: Mechanism of Decyanative Aryl-Silylation

Eric C. Keske, Thomas H. West, and Guy C. Lloyd-Jones*

ACS Catalysis, 8, 8932–8940, 2018

Analysis of Auto-induction, Inhibition and Auto-Inhibition in a Rh-Catalyzed C-C Cleavage: Mechanism of Decyanative Aryl-Silylation

151. Au-Catalyzed Oxidative Arylation: Chelation-Induced Turnover of ortho-Substituted Arylsilanes

Matthew P. Robinson and Guy C. Lloyd-Jones*

ACS Catalysis, 8, 7484–7488, 2018

Au-Catalyzed Oxidative Arylation: Chelation-Induced Turnover of ortho-Substituted Arylsilanes

150. Earth-Abundant Mixed-Metal Catalysts for Hydrocarbon Oxygenation

James R. Pankhurst, Massimiliano Curcio, Stephen Sproules,* Guy C. Lloyd-Jones,* and Jason B. Love*

Inorg. Chem., 57, 5915–5928, 2018

Earth-Abundant Mixed-Metal Catalysts for Hydrocarbon Oxygenation

149. The Dehydropolymerization of H3B·NMeH2 to form Polyaminoboranes using [Rh(Xantphos–alkyl)] Catalysts

Gemma M. Adams, Annie L. Colebatch, Joseph T. Skornia, Alasdair I. McKay, Heather C. Johnson, Guy C. Lloyd–Jones, Stuart A. Macgregor, Nicholas A. Beattie, and Andrew S. Weller*

J. Am. Chem. Soc., 140, 1481-1495, 2018

 The Dehydropolymerization of H3B·NMeH2 to form Polyaminoboranes using [Rh(Xantphos–alkyl)] Catalysts

2017

148. Base-catalyzed Aryl-B(OH)2 Protodeboronation Revisited: from Concerted Proton-Transfer to Liberation of a Transient Arylanion

Paul A. Cox, Marc Reid, Andrew G. Leach, Andrew D. Campbell, Edward J. King, and Guy C. Lloyd-Jones*

J. Am. Chem. Soc., 139, 13156–13165, 2017

Base-catalyzed Aryl-B(OH)2 Protodeboronation Revisited: from Concerted Proton-Transfer to Liberation of a Transient Arylanion

147. SHARPER reaction monitoring: generation of a narrow line- width NMR singlet, without X-pulses, in an inhomogeneous magnetic field

Ariana B. Jones, Guy C. Lloyd-Jones* and Dusan Uhrin*

Analytical Chemistry, 89, 10013–10021, 2017

SHARPER reaction monitoring: generation of a narrow line- width NMR singlet, without X-pulses, in an inhomogeneous magnetic field

146. Gold-Triggered Uncaging Chemistry in Living Systems

Ana M. Pérez-López, Belén Rubio-Ruiz, Víctor Sebastián, Lloyd Hamilton, Catherine Adam, Thomas L. Bray, Silvia Irusta, Paul M. Brennan, Guy C. Lloyd-Jones, Dirk Sieger, Jesús Santamaría,* and Asier Unciti-Broceta*

Angew. Chem. Int. Ed., 56, 12548–12552, 2017

Gold-Triggered Uncaging Chemistry in Living Systems

145. Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational Study

Thomas H. West, Daniel M. Walden, James E. Taylor, Alexander C. Brueckner, Ryne C. Johnston, Paul Ha-Yeon Cheong,* Guy C. Lloyd-Jones* and Andrew D. Smith*

J. Am. Chem. Soc., 139, 4366–4375, 2017

Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational Study

144. Au-catalyzed Biaryl Coupling to Generate 5- to 9-membered Rings: Turnover-Limiting Reductive Elimination versus π-complexation

Tom J. A. Corrie, Liam T. Ball, Christopher J. Russell and Guy C. Lloyd-Jones*

J. Am. Chem. Soc., 139, 245–254, 2017

Au-catalyzed Biaryl Coupling to Generate 5- to 9-membered Rings: Turnover-Limiting Reductive Elimination versus π-complexation

143. Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer

John J. Molloy, Thomas A. Clohessy, Craig Irving, Niall A. Anderson, Guy C. Lloyd-Jones and Allan J. B. Watson*

Chem. Sci., 8, 1551-1559, 2017

Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer

142. Formal Synthesis of (±)-Allocolchicine via Gold-Catalysed Direct Arylation: Implication of Aryl Iodine(III) Oxidant in Catalyst Deactivation Pathways

Tom J. A. Corrie and Guy C. Lloyd-Jones*

Topics in Catalysis, 60, 570-579, 2017

Formal Synthesis of (±)-Allocolchicine via Gold-Catalysed Direct Arylation: Implication of Aryl Iodine(III) Oxidant in Catalyst Deactivation Pathways

141. Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO

Rabi Chhantyal-Pun, Oliver Welz, John D. Savee, Arkke J. Eskola, Edmond P. F. Lee, Lucy Blacker, Henry R. Hill, Matilda Ashcroft, M Anwar H H. Khan, Guy C. Lloyd-Jones, Louise A Evans, Brandon Rotavera, Haifeng Huang, David L. Osborn, Daniel K.W. Mok, John M. Dyke, Dudley E. Shallcross, Carl J. Percival, Andrew J. Orr-Ewing* and Craig A. Taatjes*

J. Phys. Chem. A, 121, 4–15, 2017

Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO

2016

140. Chiral Perylene Materials by Ionic Self-Assembly

Geraldine Echue, Ian Hamley, Guy C. Lloyd-Jones and Charl F. J. Faul*

Langmuir, 32, 9023–9032, 2016

Chiral Perylene Materials by Ionic Self-Assembly

139. Protodeboronation of heteroaromatic, vinyl and cyclopropyl boronic acids: pH-rate profiles, auto-catalysis and disproportionation

Paul A. Cox, Andrew G Leach, Andrew D. Campbell and Guy C. Lloyd-Jones*

J. Am. Chem. Soc., 138, 9145–9157, 2016

Highlighted in JACS Spotlights "Untangling Aqueous Instability of Organoboronic Acids"

Protodeboronation of heteroaromatic, vinyl and cyclopropyl boronic acids: pH-rate profiles, auto-catalysis and disproportionation

138. MIDA boronates are hydrolysed fast and slow by two different mechanisms

Jorge A. Gonzalez, O. Maduka Ogba, Gregory F. Morehouse, Nicholas Rosson, Kendall N. Houk, Andrew G. Leach, Paul H.-Y. Cheong,* Martin D. Burke,* and Guy C. Lloyd-Jones*

Nature Chem., 8, 1067–1075, 2016 

Highlighted in PhysOrg "MIDA boronates react via two different mechanisms"

MIDA boronates are hydrolysed fast and slow by two different mechanisms

137. Room Temperature Gold-Catalysed Arylation of Heteroarenes: Complementarity to Palladium Catalysis

Alexander J. Cresswell and Guy C. Lloyd-Jones*

Chem Eur. J., 22, 12641–12645, 2016

Room Temperature Gold-Catalysed Arylation of Heteroarenes: Complementarity to Palladium Catalysis

136. O-Phenylisourea Synthesis and Deprotonation: Carbodiimide Elimination Precludes the Reported Chapman Rearrangement

Joseph A. Tate, George Hodges, and Guy C. Lloyd-Jones*

Eur. J. Org. Chem., 16, 2821–2827, 2016

O-Phenylisourea Synthesis and Deprotonation: Carbodiimide Elimination Precludes the Reported Chapman Rearrangement

2015

135. Pd-eta-3-C6H9 Complexes of the Trost Modular Ligand: High Nuclearity Columnar Aggregation Controlled by Concentration, Solvent and Counterion

Daugirdas Tomas Racys, Julian Eastoe, Per-Ola Norrby, Isabelle Grillo, Sarah E. Rogers and Guy C. Lloyd-Jones*

Chem. Sci., 6, 5793-5801, 2015

Pd-eta-3-C6H9 Complexes of the Trost Modular Ligand: High Nuclearity Columnar Aggregation Controlled by Concentration, Solvent and Counterion

134. Catalytic Amine Oxidation under Ambient Aerobic Conditions: Mimicry of Monoamine Oxidase B

Alexander T. Murray, Myles J. H. Dowley, Fabienne Pradaux-Caggiano, Amgalanbaatar Baldansuren, Alistair J. Fielding, Floriana Tuna, Christopher H. Hendon, Aron Walsh, Guy C. Lloyd-Jones, Matthew P. John, and David R. Carbery*

Angew. Chem. Int. Ed., 54, 8997–9000, 2015

Catalytic Amine Oxidation under Ambient Aerobic Conditions: Mimicry of Monoamine Oxidase B

133. Mechanism of Phosphine Borane Deprotection with Amines: the Effects of Phosphine, Solvent and Amine on Rate and Efficiency

Guy C Lloyd-Jones* and Nicholas P. Taylor

Chem. Eur. J., 21 ,5423-5428, 2015

*Hot Paper*

Mechanism of Phosphine Borane Deprotection with Amines: the Effects of Phosphine, Solvent and Amine on Rate and Efficiency

132. Chiral Perylene Diimides: Building Blocks for Ionic Self-Assembly

Geraldine Echue, Guy C. Lloyd-Jones and Charl F. J. Faul*

Chem. Eur. J., 21, 5118-5128, 2015

Chiral Perylene Diimides: Building Blocks for Ionic Self-Assembly